Journal of the Chemical SocietyThe Society., 1964 |
From inside the book
Results 1-3 of 73
Page 3683
... constant at any one temperature and the dielectric constant of the solvents , or solvent mixtures , concerned has helped to conceal the fundamental complexity of the problem.5c These and other considerations induced us to investigate ...
... constant at any one temperature and the dielectric constant of the solvents , or solvent mixtures , concerned has helped to conceal the fundamental complexity of the problem.5c These and other considerations induced us to investigate ...
Page 3687
... constant becomes scientifically meaningless . The reason is that the theoretical equations purporting to represent the rate constant as a function of temperature and dielectric constant only , cannot be tested even for the very simplest ...
... constant becomes scientifically meaningless . The reason is that the theoretical equations purporting to represent the rate constant as a function of temperature and dielectric constant only , cannot be tested even for the very simplest ...
Page 3694
... constant nitric acid concentration , and in the absence of added acetic acid , gave a constant rate . Moreover , the ratio of acetate : nitroxylenes ( A / N ) was constant ( 0.71 ) throughout each of these runs and from one run to ...
... constant nitric acid concentration , and in the absence of added acetic acid , gave a constant rate . Moreover , the ratio of acetate : nitroxylenes ( A / N ) was constant ( 0.71 ) throughout each of these runs and from one run to ...
Contents
4028 | 3507 |
Nucleophilic reactivity Part V The reaction between amines and ethyl meth | 3513 |
Molecular polarisability Dipole moments molar Kerr constants and apparent | 3523 |
70 other sections not shown
Other editions - View all
Common terms and phrases
absorption acetic acid acetic anhydride acetone acetoxylation acetyl added alcohol alkaline alumina aluminium Amer amine atoms band benzene benzyl bond bromide Calc carbon carbonyl CH₂ chabazite Chem chloride chloroform chromatography cm.¹ compounds concentration crystals decomp derivatives diethyl diluted dimethylformamide diol dissolved distilled dried ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtrate formation Found fraction gave give heated hydrochloric acid hydrochloride hydrogen hydrolysis hydroxyl infrared iodide isomers K₁ ketone kinetic light petroleum lithium lithium aluminium hydride m. p. and mixed mixed m. p. mixture mole molecules needles nitrate nitric acid nitrogen o-xylene obtained optical oxide oxygen petroleum b. p. phenol picrate potassium precipitated prepared proton pyridine rate constants reaction recrystallised refluxed requires residue room temperature salt sodium hydroxide solvent spectra spectrum stirred structure substitution sulphuric acid Table values washed yield