Journal of the Chemical SocietyThe Society., 1964 |
From inside the book
Results 1-3 of 70
Page 3692
... reaction ) . At first we were uncertain as to the importance of the side - reaction between nitric acid and acetic anhydride , forming ( ultimately ) tetranitromethane . Moreover , it is likely that nitrous acid ( which is produced in ...
... reaction ) . At first we were uncertain as to the importance of the side - reaction between nitric acid and acetic anhydride , forming ( ultimately ) tetranitromethane . Moreover , it is likely that nitrous acid ( which is produced in ...
Page 4339
... reaction between diazomethane and alcohol is rate - determining . Very probably the initial rapid reaction involves complex formation between diazomethane and acetone . Assuming that reactions A and B do in fact occur , we can analyse ...
... reaction between diazomethane and alcohol is rate - determining . Very probably the initial rapid reaction involves complex formation between diazomethane and acetone . Assuming that reactions A and B do in fact occur , we can analyse ...
Page 4369
... reaction , although its intermediate formation is invoked in a rationalisation of the reaction , which is accelerated by the presence of a free - radical initiator ( di- t - butyl peroxide ) . In the presence of ethanol and triethyl ...
... reaction , although its intermediate formation is invoked in a rationalisation of the reaction , which is accelerated by the presence of a free - radical initiator ( di- t - butyl peroxide ) . In the presence of ethanol and triethyl ...
Contents
4028 | 3507 |
Nucleophilic reactivity Part V The reaction between amines and ethyl meth | 3513 |
Molecular polarisability Dipole moments molar Kerr constants and apparent | 3523 |
70 other sections not shown
Other editions - View all
Common terms and phrases
absorption acetic acid acetic anhydride acetone acetoxylation acetyl added alcohol alkaline alumina aluminium Amer amine atoms band benzene benzyl bond bromide Calc carbon carbonyl CH₂ chabazite Chem chloride chloroform chromatography cm.¹ compounds concentration crystals decomp derivatives diethyl diluted dimethylformamide diol dissolved distilled dried ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtrate formation Found fraction gave give heated hydrochloric acid hydrochloride hydrogen hydrolysis hydroxyl infrared iodide isomers K₁ ketone kinetic light petroleum lithium lithium aluminium hydride m. p. and mixed mixed m. p. mixture mole molecules needles nitrate nitric acid nitrogen o-xylene obtained optical oxide oxygen petroleum b. p. phenol picrate potassium precipitated prepared proton pyridine rate constants reaction recrystallised refluxed requires residue room temperature salt sodium hydroxide solvent spectra spectrum stirred structure substitution sulphuric acid Table values washed yield