Journal of the Chemical SocietyThe Society., 1964 |
From inside the book
Results 1-3 of 75
Page 3683
... solvents , or solvent mixtures , concerned has helped to conceal the fundamental complexity of the problem.5c These and other considerations induced us to investigate how the rate of a Menschutkin reaction would behave in a single solvent ...
... solvents , or solvent mixtures , concerned has helped to conceal the fundamental complexity of the problem.5c These and other considerations induced us to investigate how the rate of a Menschutkin reaction would behave in a single solvent ...
Page 4294
... solvent , varies with the concentration . ↑ Broad , sug- gesting unresolved multiplet . Doublet . N.m.r. Spectra in Methanolic Sodium Methoxide . - In spite of the resonance absorption of the solvent it is possible to observe lines at ...
... solvent , varies with the concentration . ↑ Broad , sug- gesting unresolved multiplet . Doublet . N.m.r. Spectra in Methanolic Sodium Methoxide . - In spite of the resonance absorption of the solvent it is possible to observe lines at ...
Page 4452
... solvent - cation charge - transfer , and this is confirmed by the fact that change of solvent from water to methanol shifts the band in accordance with the difference in solvent ionisation potential . The effect of sulphate on the ...
... solvent - cation charge - transfer , and this is confirmed by the fact that change of solvent from water to methanol shifts the band in accordance with the difference in solvent ionisation potential . The effect of sulphate on the ...
Contents
4028 | 3507 |
Nucleophilic reactivity Part V The reaction between amines and ethyl meth | 3513 |
Molecular polarisability Dipole moments molar Kerr constants and apparent | 3523 |
70 other sections not shown
Other editions - View all
Common terms and phrases
absorption acetic acid acetic anhydride acetone acetoxylation acetyl added alcohol alkaline alumina aluminium Amer amine atoms band benzene benzyl bond bromide Calc carbon carbonyl CH₂ chabazite Chem chloride chloroform chromatography cm.¹ compounds concentration crystals decomp derivatives diethyl diluted dimethylformamide diol dissolved distilled dried ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtrate formation Found fraction gave give heated hydrochloric acid hydrochloride hydrogen hydrolysis hydroxyl infrared iodide isomers K₁ ketone kinetic light petroleum lithium lithium aluminium hydride m. p. and mixed mixed m. p. mixture mole molecules needles nitrate nitric acid nitrogen o-xylene obtained optical oxide oxygen petroleum b. p. phenol picrate potassium precipitated prepared proton pyridine rate constants reaction recrystallised refluxed requires residue room temperature salt sodium hydroxide solvent spectra spectrum stirred structure substitution sulphuric acid Table values washed yield