Quarterly Journal of the Chemical Society of London |
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Page 4594
... decomposition of cyclohexenyl hydroperoxide in benzene and in various olefins in the concentration range 0.03-1.4M are reported . In the olefins , decomposition proceeds by a chain mechanism involving the solvent , and characterized by ...
... decomposition of cyclohexenyl hydroperoxide in benzene and in various olefins in the concentration range 0.03-1.4M are reported . In the olefins , decomposition proceeds by a chain mechanism involving the solvent , and characterized by ...
Page 4597
... decomposition . TABLE 1 . Velocity constant [ RO , H ]。. % ( w / w ) 103k1 ( hr . - i ) 103k2 ( % peroxidic oxygen - 1 / hr . ) 5.39 6.2 1.3 3.57 3.5 1.0 3.55 4.2 1.4 2-27 3.8 1.8 1.71 2.3 1.5 0.898 1.7 2.0 0.433 0.147 0-82 0.33 2.1 ...
... decomposition . TABLE 1 . Velocity constant [ RO , H ]。. % ( w / w ) 103k1 ( hr . - i ) 103k2 ( % peroxidic oxygen - 1 / hr . ) 5.39 6.2 1.3 3.57 3.5 1.0 3.55 4.2 1.4 2-27 3.8 1.8 1.71 2.3 1.5 0.898 1.7 2.0 0.433 0.147 0-82 0.33 2.1 ...
Page 4599
... decomposed . A portion of the heated solution was transferred to a small still fitted with a cold finger " containing liquid oxygen . On gentle agitation of the solution magnetically and evacuation to 10-5 mm . , the volatile decomposition ...
... decomposed . A portion of the heated solution was transferred to a small still fitted with a cold finger " containing liquid oxygen . On gentle agitation of the solution magnetically and evacuation to 10-5 mm . , the volatile decomposition ...
Contents
Heat of Hydrolysis of Phosphorus Oxychloride and Phosphorus Trichloride | 4086 |
The Vapour Pressure of Aqueous Solutions of Beryllium Sulphate and of Uranyl | 4115 |
Determination of Individual Adsorption | 4123 |
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acetic acid acetone added alcohol alkaline alkoxide aluminium chloride Amer aniline aqueous sodium atom azoxymethane benzene boiling bond bromine Calc carbon catalyst CH₂ Chem chloroform colourless compound concentration cooled crystallised crystals cyclohexyl decomp decomposition derivative dilute dimethylberyllium dioxide dissolved distilled dried ester ethanol ether evaporated experimental extracted filtered filtrate fluoride formation formed Found fraction frequencies gave give glycol heated under reflux hydrazine hydrochloric acid hydrogen chloride hydrolysis infra-red iodide iodine isolated isomerisation ketone Light absorption light petroleum b. p. liquid m. p. and mixed method methyl mixed m. p. mixture mole molecular molecule needles nitrate nitric acid nitrogen obtained oxide potassium precipitated prepared prisms pteridine reaction requires residue room temperature salt sodium hydroxide solid soluble solution solvent spectra sulphate sulphide sulphuric acid Table uroporphyrin vapour vibration washed yellow yield zirconium